Supercritical Fluid Chromatographic Determination of Polychlorinated Biphenyls on an Octadecylsilyl-Silica Gel Column Using an Electron-Capture Detector.
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چکیده
منابع مشابه
Development of a combined solid-phase extraction-supercritical fluid extraction procedure for the determination of polychlorinated biphenyls in wastewater.
A combined solid-phase extraction (SPE)-supercritical fluid extraction (SFE) procedure was developed for the analysis of polychlorinated biphenyls (PCBs) in wastewater. The importance of cleaning and drying the filters and SPE-disks prior to eluting PCBs with SFE was studied, leading to improved recoveries for all congeners investigated. The average PCB recovery of the final procedure, at a con...
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A sensitive electron-capture gas-liquid-chromatographic method for the determination of sub-nanogram quantities of prostaglandin F(2alpha) was developed. The method is based on the sub-microgram scale conversion of the prostaglandin into the electron-capturing pentafluorobenzyl ester, and analysis of the latter as the tris-trimethylsilyl ether. The lower limit of detection was 12.5pg of the est...
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detected in these blank determinations that we were not certain whether it came from the Soluene or other sources. You may note that the blood of control rats which was analyzed with the use of Soluene did not contain detectable amounts of asbestos and zero fibers per gram was reported. We have since repeated this work (as yet unpublished) in an experiment in which asbestos was fed to rats and ...
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A precise and highly reproducible analytical method was developed for the assessment of organochlorinated pesticide and polychlorinated biphenyl residues in adipose tissue (> or = 50 mg). The method can be utilized for epidemiological studies on the significance of these environmental pollutants in the etiology of breast cancer. Supercritical fluid extraction (SFE) with CO2 and modified CO2 (ad...
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ژورنال
عنوان ژورنال: Analytical Sciences
سال: 1992
ISSN: 0910-6340,1348-2246
DOI: 10.2116/analsci.8.811